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An investigation was conducted on the performance and emissions characteristics of two Fischer-Tropsch (F-T) synthetic kerosenes, Gas-to-Liquid (GTL) S8 and Coal-to-Liquid (CTL) Iso-Paraffinic Kerosene (IPK), in a high compression ratio research engine with separate combustion chamber and using neat ULSD as a baseline. A 50% and a 70% by mass blend S8 with ULSD and a 50% and a 70% by mass blend of IPK with ULSD were analyzed for performance and emissions at 5, 6, and 7 bar Indicated Mean Effective Pressure (IMEP) and 2400 rpm. Additionally, neat S8, neat IPK, and neat ULSD were investigated in the Constant Volume Combustion Chamber (CVCC) for Ignition Delay (ID), Combustion Delay (CD), and Derived Cetane Number (DCN). S8 was found to have the highest DCN at 62 with very short ID and CD while IPK was found to have the lowest DCN at 26 and with the longest ID and CD. ULSD has a DCN between the two F-T fuels at 48. As a result of its long ID and CD, IPK showed extended regions of Low Temperature Heat Release (LTHR) and Negative Temperature Coefficient Region (NTCR) in the CVCC. It was also found that neat IPK, 50ULSD50IPK, and 30ULSD70IPK exhibit little to no ringing events at peak pressure and after High Temperature Heat Release (HTHR). In the research engine, peak heat release for ULSD, 50ULSD50S8, and 50ULSD50IPK was found to be 24.2 J/CAD, 20.5 J/CAD, and 23.4 J/CAD respectively. Due to the increase of the DCN with the addition of S8 to the blend, the 50ULSD50S8 blend exhibited minimal difference between the pre-chamber and the main chamber as it ignites earlier in the cycle with the flame front traveling quickly to the main chamber. IPK, however, had a short physical ignition delay and a long chemical ignition delay, as indicated by its low DCN, takes longer to ignite and creates a more homogeneous mixture in the highly turbulent pre-chamber. This causes a spike in heat release in the pre-chamber before the flame front propagates to the main chamber. This resulted in 50ULSD50IPK having the highest Peak Pressure Rise Rate (PPRR) and 50ULSD50S8 having the lowest PPRR. While both fuel blends reduced the soot emissions due to their low aromatic content, 50ULSD50IPK showed a 25% reduction in soot when compared to ULSD while 50ULSD50S8 showed only a 6% reduction in soot when compared to neat ULSD. There was a increase in CO emissions with the addition of IPK and a reduction in CO at low load with the addition of S8. With both F-T fuels, CO2 and NOx were found to decrease. 

An investigation of the performance and emissions of a Fischer-Tropsch Coal-to-Liquid (CTL) Iso-Paraffinic Kerosene (IPK) was conducted using a CRDI compression ignition research engine with ULSD as a reference. Due to the low Derived Cetane Number (DCN), of IPK, an extended Ignition Delay (ID), and Combustion Delay (CD) were found for it, through experimentation in a Constant Volume Combustion Chamber (CVCC). Neat IPK was analyzed in a research engine at 4 bar Indicated Mean Effective Pressure (IMEP) at three injection timings: 15°, 20°, and 25° BTDC. Combustion phasing (CA50) was matched with ULSD at 10.8° and 16° BTDC. The IPK DCN was found to be 26, while the ULSD DCN was significantly higher at 47 in a PAC CID 510. In the engine, IPK’s DCN combined with its short physical ignition delay and long chemical ignition delay compared to ULSD, caused extended duration in Low Temperature Heat Release (LTHR) and cool flame formation. It was found in an analysis of the Apparent Heat Release Rate (AHRR) curve for IPK that there were multiple Negative Temperature Coefficient (NTCR) regions before the main combustion event. The High Temperature Heat Release (HTHR) of IPK achieved a greater peak heat release rate compared to ULSD. Pressure rise rate for IPK was observed to increase significantly with increase in injection timing. The peak in-cylinder pressure was also greater for IPK when matching CA50 by varying injection timing. Emissions analysis revealed that IPK produced less NO_x, soot, and CO₂ compared to ULSD. CO and UHC emissions for IPK increased. 

Similar to most wetlands, the Florida Everglades landscape was altered to promote agriculture and human settlement, significantly altering the natural hydrologic regime. Once former agricultural land located within Everglades National Park (ENP), the Hole-in-the-Donut (HID) wetland restoration program became the first mitigation bank project in Florida. The HID program utilized a restoration technique of complete soil removal to effectively eradicate an invasive plant species. This research investigated the effects of the vegetation and soil removal on the hydrologic conditions of the HID, specifically evapotranspiration and water chemistry. Annual evapotranspiration rates were determined for the region using remotely sensed data and compared to the acres restored over a 15-year period. Groundwater and surface waters were collected from both inside the HID and from adjacent areas within ENP for major cations and anions and total nutrient concentrations. Evapotranspiration rates were found to decrease from a mean of 1083.4 mm year−1 in the year 2000 to 891.6 mm year−1 in 2014 as the restored area increased to 4893 acres. Concentrations of ions and nutrients were lower in groundwater and surface water within the restored areas compared to adjacent areas. We conclude that the lack of soil cover (along with reduced evapotranspiration rates) contributed to the lower ion and nutrient concentrations in the surface water and groundwater within the HID.